Projects / Programmes
Nuclear magnetic resonance in nanoporous molecular sieves
Code |
Science |
Field |
Subfield |
1.04.00 |
Natural sciences and mathematics |
Chemistry |
|
Code |
Science |
Field |
P360 |
Natural sciences and mathematics |
Inorganic chemistry |
P260 |
Natural sciences and mathematics |
Condensed matter: electronic structure, electrical, magnetic and optical properties, supraconductors, magnetic resonance, relaxation, spectroscopy |
solid-state nuclear magnetic resonance, quadrupolar nuclei, zeolitic materials, micro- and meso-porous molecular sieves, structural properties, isomorphous substitution
Researchers (2)
no. |
Code |
Name and surname |
Research area |
Role |
Period |
No. of publicationsNo. of publications |
1. |
18206 |
Edi Kranjc |
|
Technical associate |
2004 - 2006 |
0 |
2. |
18146 |
PhD Gregor Mali |
Physics |
Head |
2004 - 2007 |
0 |
Organisations (1)
no. |
Code |
Research organisation |
City |
Registration number |
No. of publicationsNo. of publications |
1. |
0104 |
National Institute of Chemistry |
Ljubljana |
5051592000 |
10 |
Abstract
Within the frame of the proposed project existing solid-state nuclear magnetic resonance methods shall be optimized and new ones shall be developed and then used for the investigation of structural properties of nanoporous molecular sieves. The methodological development shall be focused on homo- and heteronuclear correlation spectroscopy of quadrupolar nuclei in polycrystalline and amorphous materials. Nuclear magnetic resonance measurements shall improve our knowledge about the framework of micro- and mesoporous materials as well as about the interaction of molecular sieve frameworks with extra-framework molecules. Potential and limitations of nuclear magnetic resonance spectroscopy for the investigation of isomorphous substitution in molecular sieves shall be determined. Magnetic resonance and X-ray absorption spectroscopy on a series of molecular sieves, modified by different transition metals, shall help us to better understand the incorporation of transition-metal atoms into the molecular sieve framework. The investigations shall also help us to predict catalytic properties of new molecular sieves.