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Projects / Programmes source: ARIS

Nuclear magnetic resonance in nanoporous molecular sieves

Research activity

Code Science Field Subfield
1.04.00  Natural sciences and mathematics  Chemistry   

Code Science Field
P360  Natural sciences and mathematics  Inorganic chemistry 
P260  Natural sciences and mathematics  Condensed matter: electronic structure, electrical, magnetic and optical properties, supraconductors, magnetic resonance, relaxation, spectroscopy 
Keywords
solid-state nuclear magnetic resonance, quadrupolar nuclei, zeolitic materials, micro- and meso-porous molecular sieves, structural properties, isomorphous substitution
Evaluation (rules)
source: COBISS
Researchers (2)
no. Code Name and surname Research area Role Period No. of publicationsNo. of publications
1.  18206  Edi Kranjc    Technical associate  2004 - 2006 
2.  18146  PhD Gregor Mali  Physics  Head  2004 - 2007 
Organisations (1)
no. Code Research organisation City Registration number No. of publicationsNo. of publications
1.  0104  National Institute of Chemistry  Ljubljana  5051592000  10 
Abstract
Within the frame of the proposed project existing solid-state nuclear magnetic resonance methods shall be optimized and new ones shall be developed and then used for the investigation of structural properties of nanoporous molecular sieves. The methodological development shall be focused on homo- and heteronuclear correlation spectroscopy of quadrupolar nuclei in polycrystalline and amorphous materials. Nuclear magnetic resonance measurements shall improve our knowledge about the framework of micro- and mesoporous materials as well as about the interaction of molecular sieve frameworks with extra-framework molecules. Potential and limitations of nuclear magnetic resonance spectroscopy for the investigation of isomorphous substitution in molecular sieves shall be determined. Magnetic resonance and X-ray absorption spectroscopy on a series of molecular sieves, modified by different transition metals, shall help us to better understand the incorporation of transition-metal atoms into the molecular sieve framework. The investigations shall also help us to predict catalytic properties of new molecular sieves.
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